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I have to run for the bus, but do a net search on

Greek Fire

It's supposedly like a napalm type substance thet you can not extinguish. The Byzantines were alledged to have fired it in early flame throwers.

Perhaps the ancient Scots knew about natural gas and used that :-)

I'd forgotten about Greek Fire, will have a mooch.
Maybe they just ate a lot of Prehistoric beans on toast (ala Blazing saddles).

Perhaps someone should ask the Viatnamese if napalm caused similar effects to some of their stone buildings!
I think that the problem lies in concentrating the heat, even in modern pottery kilns it doesn't melt the clay only the glaze which has a lower melting point. I'm sure we have all seen the "reconstructions" on tv where they try to make Bronze/Iron Age tools, the heat required is considerable yet I haven't seen much vitrification of the oven interior.
I once used salvaged bricks from a demolished brickworks oven, they were well baked! but showed little sign of a glassy finish. I think that "vitrified" brick has an extra finish applied to the exterior.

Are there any sites down south showing this? Does it depend on rock type? So many questions-so few answers.

Love it! :-)